反応式
[CH:1](=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.NC1C(C)=CC=CN=1.N[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.C(O)(=O)C1C=CC=CC=1.C=CCCCC.C1(C)C=CC=CC=1>>[C:1]([C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)(=[O:8])[CH2:22][CH2:23][CH2:18][CH2:19][CH2:20][CH3:21]参加物
7
実験手順
Under the same reaction procedure and conditions as in Example 1 (benzaldehyde 0.5 mmol, 2-amino-3-picoline 0.1 mmol, aniline 0.3 mmol, bezoic acid 0.03 mmol, 1-hexene 2.5 mmol, toluene 0.87 mmol), the mixture in a 500 ml pressure reactor was stirred at normal temperature for 2-3 minutes and then combined with Rh(PPh3)3Cl 0.01 mmol. While the reactor was stopped with a stopper, the reactants were stirred at 130 ° C. for various reaction times as shown in the following table 9. After completion of the reaction, gas chromatography was conducted to determine the yields of heptanophenone, products according to various period of times and the results are given in Table 9, below.
後処理
- stirringthe reactants were stirred at 130 ° C. for various reaction times
- customAfter completion of the reaction, gas chromatography
出典と根拠
- ORDレコード
- ord-6d0b7f1629d24a4bbff19960937cbd29
- 出典データセット
- uspto-grants-2002_03
- 特許番号
- US06353139B1
関連ノート
読み込み中…