2,3,5-Trimethylphenol → 2,3,5-Trimethyl-phenyl ethyl ether

HRID 27855

反応式

HRID 27855 の反応式
[Cl-].[CH2:2]([O:4][C:5]1[CH:30]=[C:29]([CH3:31])[C:8](C[P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=[C:7]([CH3:32])[C:6]=1[CH3:33])[CH3:3].CC1C(C)=CC(C)=CC=1O>>[CH2:2]([O:4][C:5]1[CH:30]=[C:29]([CH3:31])[CH:8]=[C:7]([CH3:32])[C:6]=1[CH3:33])[CH3:3]

参加物

3

反応物 2

HCID 127692,3,5-TrimethylphenolHCID 867359014-Ethoxy-2,3,6-trimethyl-benzyl-triphenylphosphonium chloride

生成物 1

HCID 202100102,3,5-Trimethyl-phenyl ethyl ether

実験手順

The 4-ethoxy-2,3,6-trimethyl-benzyl-triphenylphosphonium chloride employed as the starting material is prepared by the procedure described in Example 18 by alkylation of 2,3,5-trimethylphenol to give 2,3,5-trimethyl-phenyl ethyl ether (melting point 93°-95° C.), by haloformylation of the ether obtained to give 4-ethoxy-2,3,6-trimethyl-benzyl chloride (melting point 63°-64° C.) and by reaction of the latter compound with triphenylphosphine.

後処理

  1. customis prepared by the procedure

出典と根拠

ORDレコード
ord-3dae91d07f994f6abbe906618bf1815a
出典データセット
uspto-grants-1980_09
特許番号
US04224244

関連ノート

読み込み中…