3-Bromo-1-indanone → 1H-inden-1-one

HRID 279153

反応式

HRID 279153 の反応式
Br[CH:2]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4](=[O:11])[CH2:3]1>C(OCC)C>[C:4]1(=[O:11])[C:5]2[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=2)[CH:2]=[CH:3]1

参加物

3

反応物 1

HCID 117459123-Bromo-1-indanone

生成物 1

HCID 118153841H-inden-1-one

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

3-Bromoindan-1-one (1.5) was dissolved in diethyl ether (10 ml). The temperature was kept at +2-+4 while TEA (2.7 ml) was added. The resulting mixture was further stirred at +2-+4 for 2 hours. The precipitated salt was filtered off and the filtrate evaporated. The crude inden-1-one was used for further reaction without purification. Yield was 0.9 g.

後処理

  1. additionwas added
  2. filtrationThe precipitated salt was filtered off
  3. customthe filtrate evaporated
  4. customThe crude inden-1-one was used for further reaction without purification

出典と根拠

ORDレコード
ord-099caa22924f4e3cb6b0fef9973b9406
出典データセット
uspto-grants-2002_03
特許番号
US06362211B1

関連ノート

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