N-Phenylhydroxylamine → 1-(4-chlorophenyl)-N-phenylmethanimine oxide

HRID 27919

反応式

HRID 27919 の反応式
[C:1]1([NH:7][OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:9][C:10]1[CH:25]=[CH:24][C:13]([CH:14]=NC2C=CC(Cl)=CC=2C)=[CH:12][CH:11]=1>CCOCC>[Cl:9][C:10]1[CH:25]=[CH:24][C:13]([CH:14]=[N+:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[O-:8])=[CH:12][CH:11]=1

参加物

4

反応物 2

HCID 7518N-PhenylhydroxylamineHCID 13017552N-(p-Chlorobenzylidene)-2-methyl-4-chloroaniline

生成物 1

HCID 2545041-(4-chlorophenyl)-N-phenylmethanimine oxide

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒2 回

実験手順

N-phenylhydroxylamine (0.052 mole) was dissolved in ether (20 cc). This solution was treated with N-(p-chlorobenzylidene)-2-methyl-4-chloroaniline (13.8 g.) dissolved in ether (50 cc). After 15 min., white crystals had begun to form. Filtration and washing with ether gave α-p-chlorophenyl-N-phenylnitrone.

後処理

  1. customto form
  2. filtrationFiltration
  3. washwashing with ether

出典と根拠

ORDレコード
ord-0e12529043b64c969cf8dc80bad688c5
出典データセット
uspto-grants-1980_09
特許番号
US04224340

関連ノート

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