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Methane → Cyclohexyl isocyanate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methane | HCID 297 | — |
| 反応物 | 1-Naphthol | HCID 7005 | — |
| 反応物 | Cyclohexylamine | HCID 7965 | — |
| 触媒 | Tetraethylammonium Iodide | HCID 6225 | — |
| 触媒 | Rhodium | HCID 23948 | — |
| 生成物 | Cyclohexyl isocyanate | HCID 18502 | — |
反応手順
The carbonylation reaction is conducted in the same manner as in Example 1 except that 25 mmol of cyclohexylamine, 86 g of α-naphthol, 1.5 g of Rh/C having 5% Rh carried on activated charcoal and 1 mmol of tetraethylammonium iodide are employed. As a result, the yields of cyclohexyl isocyanate and α-naphthyl cyclohexyl carbamate are 58% and 10%, respectively.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04587056 |
| 出典データセット | uspto-grants-1986_05 |
| ORD ID | ord-df5d85d8c97f4f9bbfa76d696c7c7942 |
| 出典メモ | uspto-grants-1986_05 |