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Guanidine → 2-Amino-4-methoxy-6-methyl-1,3,5-triazine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Guanidine | HCID 3520 | — |
| 反応物 | 1,3,5-Triazin-2-amine | HCID 20077 | — |
| 反応物 | O-Methylisourea | HCID 75544 | — |
| 生成物 | 2-Amino-4-methoxy-6-methyl-1,3,5-triazine | HCID 15466 | — |
| 生成物 | O-Methylisourea | HCID 75544 | — |
反応手順
According to U.S. Pat. No. 3,754,547, 2-amino-s-triazine derivatives can be prepared by reaction of N-cyanimido-esters with guanidine, O-methylisourea or amides. This process is also unsuitable on an industrial scale, since the yields produced are only about one-half of the desired yield (a maximum yield of 45% results in the case of the important compound 2-amino-4-methoxy-6-methyl-s-triazine), and the free O-methylisourea base, which is relatively unstable, must be used as the starting substance in this process.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04587337 |
| 出典データセット | uspto-grants-1986_05 |
| ORD ID | ord-0e24c445cce340e38a86658ee8b286ff |
| 出典メモ | uspto-grants-1986_05 |