化工社化工社 化学情報印刷レポート · 研究参考用
Benzene → Tetraethylammonium 4-Nitrophenolate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzene | HCID 241 | — |
| 反応物 | 4-Nitrophenol | HCID 980 | — |
| 反応物 | Tetraethylammonium Hydroxide | HCID 6509 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | Tetraethylammonium 4-Nitrophenolate | HCID 23322207 | 94.7% |
反応手順
A mixture of 4-nitrophenol (13.9 g, 0.10 mol) and benzene (250 mL) was treated with tetraethylammonium hydroxide (14.7 g, 0.10 mol), added as a 20% aqueous solution. The mixture was heated under reflux until all water was removed by azeotropic distillation. The solution was allowed to cool with continued stirring. Upon standing, 25.4 g of a yellow solid was obtained; it was recrystallized from THF. 1H NMR (CDCl3) confirmed the title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04588795 |
| 出典データセット | uspto-grants-1986_05 |
| ORD ID | ord-ee8ea755095f40dfa79c74726b8d381f |
| 出典メモ | uspto-grants-1986_05 |