Ethylene → Ethylene/Vinyl Acetate Maleic Anhydride

反応式

C=C.[C:3](OC=C)(=O)[CH3:4].[C:9]1(=[O:15])[O:14][C:12](=[O:13])[CH:11]=[CH:10]1>>[CH2:3]=[CH2:4].[C:12]([O:14][CH:9]=[CH2:10])(=[O:13])[CH3:11].[C:12]1(=[O:13])[O:14][C:9](=[O:15])[CH:10]=[CH:11]1

参加物

反応物 3

HCID 6325Ethylene

HCID 7904Vinyl Acetate

HCID 7923Maleic Anhydride

生成物 1

HCID 86650683Ethylene/Vinyl Acetate Maleic Anhydride

実験手順

A terpolymer containing 60.3 percent ethylene, 38 weight percent vinyl acetate, and 1.7 percent maleic anhydride, and displaying a melt index of 220 g./10 min. was prepared at the rate of 0.68 kg./hr. in a continuous 0.72-liter stirred autoclave by the following procedure. Monomers were mixed, pressured to 1900 kg./sq. cm., and fed at these rates: