化工社化工社 化学情報印刷レポート · 研究参考用
Water → 1-Azido-1-(3-furyl)-1-(4-methyl-5-oxazolyl)ethane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Boron trifluoride | HCID 6356 | — |
| 反応物 | Azidotrimethylsilane | HCID 78378 | — |
| 反応物 | 1-(3-Furyl)-1-(4-methyl-5-oxazolyl)ethanol | HCID 9794153 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | 1-Azido-1-(3-furyl)-1-(4-methyl-5-oxazolyl)ethane | HCID 18936294 | — |
反応手順
1-(3-Furyl)-1-(4-methyl-5-oxazolyl)ethanol (1 g) was suspended in benzene (4 ml). Trimethylsilylazide (822 μl) was added followed by boron trifluoride diethyletherate (770 μl). The mixture was stirred overnight at room temperature, then poured into water and extracted to give the title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05731335 |
| 出典データセット | uspto-grants-1998_03 |
| ORD ID | ord-d5df902db51f4973b3595b8e30064e32 |
| 出典メモ | uspto-grants-1998_03 |