Lawesson's reagent → 5-(3-Bromo-5-nitrophenyl)-5-methylmorpholine-3-thione

反応式

[Br:1][c:2]1[cH:3][c:4]([C:11]2([CH3:18])[NH:12][C:13](=[O:17])[CH2:14][O:15][CH2:16]2)[cH:5][c:6]([N+:8](=[O:9])[O-:10])[cH:7]1.[CH3:19][O:20][c:21]1[cH:22][cH:23][c:24]([P:25]2(=[S:28])[S:26][P:27]([c:29]3[cH:30][cH:31][c:32]([O:33][CH3:34])[cH:35][cH:36]3)(=[S:37])[S:38]2)[cH:39][cH:40]1>>[Br:1][c:2]1[cH:3][c:4]([C:11]2([CH3:18])[NH:12][C:13](=[S:28])[CH2:14][O:15][CH2:16]2)[cH:5][c:6]([N+:8](=[O:9])[O-:10])[cH:7]1

参加物

反応物 2

HCID 87949Lawesson's reagent

HCID 666660355-(3-Bromo-5-nitrophenyl)-5-methylmorpholin-3-one

生成物 1

HCID 870965245-(3-Bromo-5-nitrophenyl)-5-methylmorpholine-3-thione

出典と根拠

ORDレコード: ord-c827cbc6005f420782a328a05b44d249
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (8/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…