m-Anisoyl chloride → N-(6-bromo-2,3,4,9-tetrahydro-1H-carbazol-1-yl)-3-methoxybenzamide

関与物質

反応手順

N-(6-Bromo-2,3,4,9-tetrahydro-1H-carbazol-1-yl)-3-methoxybenzamide was prepared from 6-bromo-2,3,4,9-tetrahydro-1H-carbazol-1-amine and m-anisoyl chloride in a similar manner as described above to give an orange solid (49% yield). 1H-NMR (CDCl3): δ 8.92 (s, 1H), 7.61 (m, 1H), 7.38-7.30 (m, 2H), 7.30-7.25 (m, 1H), 7.23 (m, 1H), 7.17 (d, 1H), 7.08-7.02 (m, 1H), 6.39 (d, 1H), 5.32 (m, 1H), 3.85 (s, 3H), 2.72 (m, 2H), 2.31 (m, 1H), 1.97 (m, 3H); MS m/z 399 (M−1).

情報源と証拠