Methanesulfonic Acid → Methanesulfonate

HRID 2893

反応式

HRID 2893 の反応式
[NH2:1][C:2]([NH2:22])=[N:3][C:4](=[O:21])[C:5]1[CH:10]=[C:9]([S:11]([CH3:14])(=[O:13])=[O:12])[C:8]([CH:15]2[CH2:19][CH2:18][CH:17]=[CH:16]2)=[CH:7][C:6]=1[CH3:20].[CH3:23][S:24]([OH:27])(=[O:26])=[O:25]>CC(C)=O>[NH2:22][C:2]([NH2:1])=[N:3][C:4](=[O:21])[C:5]1[CH:10]=[C:9]([S:11]([CH3:14])(=[O:12])=[O:13])[C:8]([CH:15]2[CH2:19][CH2:18][CH:17]=[CH:16]2)=[CH:7][C:6]=1[CH3:20].[CH3:23][S:24]([O-:27])(=[O:26])=[O:25]

参加物

5

反応物 2

HCID 6395Methanesulfonic AcidHCID 9818569N-diaminomethylene-2-methyl-4-(1-cyclopenten-3-yl)-5-methylsulfonylbenzamide

生成物 2

HCID 85257MethanesulfonateHCID 9818569N-diaminomethylene-2-methyl-4-(1-cyclopenten-3-yl)-5-methylsulfonylbenzamide

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

700 mg of N-diaminomethylene-2-methyl-4-(1-cyclopenten-3-yl)-5-methylsulfonylbenzamide [which can be prepared according to Example 1; m.p. 212°-214°] are dissolved in 20 ml of acetone, and 6.1 ml of methanesulfonic acid are added, while stirring. Filtration and lyophilization give N-diaminomethylene-2-methyl-4-(1-cyclopenten-3-yl)-5-methylsulfonylbenzamide, methane-sulfonate, m.p. 202°-204°.

後処理

  1. filtrationFiltration and lyophilization

出典と根拠

ORDレコード
ord-0c4cda8c04324a8b924c6c3506ced1f7
出典データセット
uspto-grants-1998_03
特許番号
US05731351

関連ノート

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