化工社化工社 化学情報印刷レポート · 研究参考用
Benzoyl Peroxide → Ethyl 3-bromo-4-(bromomethyl)benzoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzoyl Peroxide | HCID 7187 | — |
| 反応物 | N-bromobutanimide | HCID 67184 | — |
| 反応物 | Ethyl 3-bromo-4-methylbenzoate | HCID 14945865 | — |
| 溶媒 | Carbon Tetrachloride | HCID 5943 | — |
| 生成物 | Ethyl 3-bromo-4-(bromomethyl)benzoate | HCID 13877460 | — |
反応手順
A mixture of 1.0 mmol of ethyl 3-bromo-4-methylbenzoate, 1.0 mmol NBS, and 0.02 mmol benzoyl peroxide in 5 mL CCl4 was refluxed for 4 h and then processed by filtration and chromatography to provide ethyl 3-bromo-4-bromomethylbenzoate as an oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05731432 |
| 出典データセット | uspto-grants-1998_03 |
| ORD ID | ord-43fc139c41d84237a967f7fa62214d1c |
| 出典メモ | uspto-grants-1998_03 |