関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Allyltributylstannane | HCID 90628 | — |
| 反応物 | 2-Chloromethyl 2-(trimethylsilyl)ethyl ether | HCID 2724271 | — |
| 反応物 | 5-(3-Bromo-4-methylphenyl)-2H-tetrazole | HCID 178418249 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | n-Trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole | HCID 69840625 | — |
反応手順
A solution of 1.0 mmol of this tetrazole, 2.0 mmol of SEMCl in 10 mL DMF was stirred for 1 h. 2.0 mmol of allyltributyltin and 0.1 mmol of Pd(Ph3)4 was added and heated at 70° C. for 14 h. Chromatography provided N-trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05731432 |
|---|
| 出典データセット | uspto-grants-1998_03 |
|---|
| ORD ID | ord-23c1255e56f24480bb48d53be97ec0f6 |
|---|
| 出典メモ | uspto-grants-1998_03 |
|---|
