関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Cyclooctylamine | HCID 2903 | — |
| 反応物 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 反応物 | Trimesoyl chloride | HCID 78138 | — |
| 反応物 | Lithium Chloride | HCID 433294 | — |
| 溶媒 | Pyridine | HCID 1049 | — |
| 生成物 | 1,3,5-Benzenetricarboxylic acid tris(cyclooctylamide) | HCID 59789613 | — |
反応手順
4.20 g (33 mmol) of cyclooctylamine and 0.1 g of dry LiCl are added under inert atmosphere to 70 ml of dry NMP and 15 ml of dry pyridine and cooled to 5° C. Then, 2.39 g (9 mmol) of 1,3,5-benzenetricarboxylic acid trichloride are added. The reaction mixture is heated to 75° C. and stirred. After 2 hours the reaction mixture is added to 300 ml of ice water. Customary work-up (recrystallization from N,N-dimethylformamide) gives 1,3,5-benzenetricarboxylic acid tris(cyclooctylamide).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07423088B2 |
|---|
| 出典データセット | uspto-grants-2008_09 |
|---|
| ORD ID | ord-0249888884cf4a97b3e2384f1b38319c |
|---|
| 出典メモ | uspto-grants-2008_09 |
|---|
