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Water → N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | 1,2-Diethylbenzene | HCID 8657 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 反応物 | N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide | HCID 59793205 | — |
| 溶媒 | Hexane | HCID 8058 | — |
| 生成物 | N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine | HCID 59793193 | 85.5% |
反応手順
Charged were N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide 82.0 g, a 50% potassium hydroxide aqueous solution 39 g and diethylbenzene 100 ml, and the mixture was heated and refluxed for 3 days. After finishing the reaction, the mixture was left cooling down, and water 100 ml and hexane 500 ml were added thereto. The brown solid matter deposited was filtered off and dried under reduced pressure to obtain 67 g of N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07425654B2 |
| 出典データセット | uspto-grants-2008_09 |
| ORD ID | ord-86bb213d299e42d6ac8e1d5218b776b3 |
| 出典メモ | uspto-grants-2008_09 |