関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dimethylalumanylium chloride | HCID 16686359 | — |
| 反応物 | Lithium pentamethylcyclopentadiene | HCID 67305831 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | Dimethyl(pentamethylcyclopentadienyl)aluminum | HCID 16708437 | 78% |
反応手順
1.14 g of lithium pentamethylcyclopentadiene (C5Me5Li) and 50 ml of toluene were added into a 100-ml Schlenk flask bottle at room temperature. Then 8 ml of dimethylaluminum chloride (1M in hexane) was added to the mixture. The mixture solution was heated at 80° C. for four hours. After the removal of LiCl, the filtrate was vacuum dried to obtain a yellowish dimethyl(pentamethylcyclopentadienyl)aluminum. The yield was 78%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06211106B1 |
|---|
| 出典データセット | uspto-grants-2001_04 |
|---|
| ORD ID | ord-4e0a52e81c3946bc92d8d6cbb03edb98 |
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| 出典メモ | uspto-grants-2001_04 |
|---|
