化工社化工社 化学情報印刷レポート · 研究参考用
Hydrochloric Acid → HCID 178418386、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Ethyl 2,4-dioxo-4-(2,4,6-trimethylphenyl)butanoate | HCID 14945000 | — |
| 反応物 | Sodium Nitrite | HCID 23668193 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | HCID 178418386 | HCID 178418386 | — |
反応手順
N2O3 gas was slowly passed into a stirred solution of the product of step A (16.2 g) in 300 mL of ethanol until the disappearance of starting material was confirmed by TLC. N2O3 gas was generated by the dropwise addition of 12N aqueous HCl solution into an aqueous slurry of NaNO2. The solvent was removed from the mixture and 200 mL of water was added to the residue. The product was then extracted into ether. The ether extract was dried over Na2SO4 and evaporated to give 16.1 g of a semi-solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06211187B1 |
| 出典データセット | uspto-grants-2001_04 |
| ORD ID | ord-2c0368633ec242138ca06c698cd783de |
| 出典メモ | uspto-grants-2001_04 |