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2-Acetylnaphthalene → N-[1-(2-naphthyl)ethyl]-1-(3-methoxyphenyl)ethylamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Acetylnaphthalene | HCID 7122 | — |
| 反応物 | 1-(3-Methoxyphenyl)ethanamine | HCID 4612058 | — |
| 触媒 | Titanium isopropoxide | HCID 11026 | — |
| 生成物 | N-[1-(2-naphthyl)ethyl]-1-(3-methoxyphenyl)ethylamine | HCID 22011059 | — |
反応手順
In a similar fashion equal molar amounts 1-(3-methoxyphenyl)ethylamine (1.51 g, 10 mmol), 2′-acetonaphthone (1.70 g, 10 mmol) and 1.25 equivalents of titanium(IV) isopropoxide (3.55 g, 12.5 mmol) were treated as above. Work-up yielded N-[1-(2-naphthyl)ethyl]-1-(3-methoxyphenyl)ethylamine, 6F, as a clear, colorless oil; m/z (rel. int.) 305 (M+, 1), 290 (35), 170 (49), 155 (100), 135 (55), 115 (8), 105 (10), 91 (9), 77 (10).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06211244B1 |
| 出典データセット | uspto-grants-2001_04 |
| ORD ID | ord-4464b040a8584a058b6e9f2f05b92b04 |
| 出典メモ | uspto-grants-2001_04 |