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Triethylamine → 1-[(4-Methylthiophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | 4-(Methylsulfanyl)thiophenol | HCID 136896 | — |
| 反応物 | Propanehydrazonoyl chloride, N-(4-methoxyphenyl)-2-oxo- | HCID 2844936 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 1-[(4-Methylthiophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone | HCID 53800153 | — |
反応手順
A suspension of 31.7 g (0.139 mol)of 1-chloro-1-[(4-methoxyphenyl)hydrazono]-2-propanone in 400 ml of ethanol was treated with 23.4 g of 4-methylthiothiophenol and 23.4 of triethylamine. The suspension was heated at reflux for 2 hours and cooled. The resultant suspension was filtered and the precipitate was washed with 1 portion of cold ethanol. The solids were dried in vacuo to yield 1-[(4-methylthiophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone, mp 124-127° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06214809B1 |
| 出典データセット | uspto-grants-2001_04 |
| ORD ID | ord-b4646b47587d404b9cbe0017b27c7b36 |
| 出典メモ | uspto-grants-2001_04 |