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Triphenylphosphine → 3-Amino-1-(diphenylmethyl)azetidine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triphenylphosphine | HCID 11776 | — |
| 反応物 | 3-Azido-1-benzhydrylazetidine | HCID 15512652 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 3-Amino-1-(diphenylmethyl)azetidine | HCID 5744546 | — |
反応手順
A solution of 10 (5.7 g, 21.6 mmol), triphenylphosphine (11.3 g, 43 mmol) and water (5 ml) was heated to reflux for 24 hours. After cooling to room temperature the solvent was removed in vacuo and the residue purified by chromatography on silica gel (90:9:1 CHCl3:MeOH:NH4OH).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06214832B1 |
| 出典データセット | uspto-grants-2001_04 |
| ORD ID | ord-f60b66a271f9493a9e18eb43c1e0e25d |
| 出典メモ | uspto-grants-2001_04 |