化工社化工社 化学情報印刷レポート · 研究参考用
5-Decene → 1-Hexene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 5-Decene | HCID 23916 | — |
| 反応物 | 9-Decen-1-ol | HCID 25612 | — |
| 反応物 | 9-Tetradecenyl formate | HCID 92065 | — |
| 触媒 | HCID 178479819 | HCID 178479819 | — |
| 生成物 | 1-Hexene | HCID 11597 | — |
| 生成物 | Tetradec-9-en-1-ol | HCID 37064 | — |
反応手順
FIG. 9 shows a synthesis of 9-tetradecenyl formate, in which 5-decene is cross-metathesized with 9-decenol in the presence of Grubbs' catalyst to produce 9-tetradecenol while 1-hexene is removed from the reaction under vacuum, and in which the metathesis product, 9-tetradecenol, is reacted with formyl acetate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06215019B1 |
| 出典データセット | uspto-grants-2001_04 |
| ORD ID | ord-615d473a08ae41e085a0065bbcfdf238 |
| 出典メモ | uspto-grants-2001_04 |