関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1-Phenylethanol | HCID 7409 | — |
| 反応物 | Benzenemethanol, 4-chloro-alpha-methyl- | HCID 18825 | — |
| 反応物 | 1-(4-Bromophenyl)ethanol | HCID 95352 | — |
| 反応物 | alpha-Methylnaphthalene-2-methanol | HCID 98243 | — |
| 反応物 | 1-(4-Methoxyphenyl)ethanol | HCID 101148 | — |
| 反応物 | 1-(4-Nitrophenyl)ethan-1-ol | HCID 592376 | — |
| 生成物 | p-Bromoacetophenone | HCID 7466 | — |
| 生成物 | P-Chloroacetophenone | HCID 7467 | — |
| 生成物 | 4'-Methoxyacetophenone | HCID 7476 | — |
| 生成物 | p-Nitroacetophenone | HCID 7487 | — |
反応手順
By using the equipment analysis described above, the retention times of (±)-1-(4-bromophenyl)ethanol were confirmed to be 10.447 for the S form and 11.031 for the R form, those of (±)-1-(4-chlorophenyl)ethanol 9.936 for the S form and 10.355 for the R form, those of (±)-1-phenylethanol 11.958 for the S form and 13.133 for the R form, those of (±)-1-(2-naphthyl)ethanol 15.693 for the S form and 17.049 for the R form, those of (±)-1-(4-methoxyphenyl)ethanol 9.165 for the S form and 10.781 for the R form, and those of (±)-1-(4-nitrophenyl)ethanol 18.923 for the R form and 19.562 for the S form. In addition, the retention times of 4-bromoacetophenone, 4-chloroacetophenone, 4-methoxyacetophenone and 4-nitroacetophenone that are formed by oxidation of each substrate were similarly confirmed to be 13.122, 10.304, 17.169 and 37.208, respectively.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06218581B1 |
|---|
| 出典データセット | uspto-grants-2001_04 |
|---|
| ORD ID | ord-0746ec2909564f6e9270cd1fd5cc85b5 |
|---|
| 出典メモ | uspto-grants-2001_04 |
|---|
