化工社化工社 化学情報印刷レポート · 研究参考用
1-Phenylethanol → 1-Phenylethanol, (S)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Phenylethanol | HCID 7409 | — |
| 反応物 | Acetophenone | HCID 7410 | — |
| 反応物 | 1-Phenylethanol, (R)- | HCID 637516 | — |
| 生成物 | 1-Phenylethanol, (S)- | HCID 443135 | 61% |
反応手順
As shown here, the biochemical conversion reaction of immobilized green pea protein for the substrate (±)-1-phenylethanol (201 mg) requires 6 days by going through bioconversion to acetophenone accompanying sterically selective oxidation of (R)-1-phenylethanol to obtain 122 mg of (S)-1-phenylethanol at a yield of 61%. Optical purity was obtained at 98% e.e.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06218581B1 |
| 出典データセット | uspto-grants-2001_04 |
| ORD ID | ord-6d584782475d4c34bac67076c47702c2 |
| 出典メモ | uspto-grants-2001_04 |