化工社化工社 化学情報印刷レポート · 研究参考用
Benzoic Acid → Benzoyl fluoride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzoic Acid | HCID 243 | — |
| 反応物 | Diphenylaminosulfur trifluoride | HCID 9859911 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Benzoyl fluoride | HCID 67999 | 99.9% |
反応手順
A solution of benzoic acid (122 mg, 1 mmol) in CH2Cl2 (5.0 mL) was added to diphenylaminosulfur trifluoride (771 mg, 3.0 mmol ) under N2 and stirred for 16 h at room temperature. After work-up as above benzoyl fluoride (124 mg, quantitative yield) was obtained. The product was identified by g.c.m.s. M+=124
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06222064B1 |
| 出典データセット | uspto-grants-2001_04 |
| ORD ID | ord-a908a86135bb47f298ee905e61b0d722 |
| 出典メモ | uspto-grants-2001_04 |