化工社化工社 化学情報印刷レポート · 研究参考用
Glycidyl methacrylate → 3-(Methacryloyloxy)-2-hydroxypropyl methyl-5-carbomethoxybicyclo-[2.2.1]hept-2-ene-6-carboxylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Glycidyl methacrylate | HCID 7837 | — |
| 反応物 | 2,6-Di-tert-butyl-4-methylphenol | HCID 31404 | — |
| 反応物 | Methyl-5-carbomethoxybicyclo [2.2.1]hept-2-ene-6-carboxylic acid | HCID 54301392 | — |
| 触媒 | Tetramethylammonium chloride | HCID 6379 | — |
| 生成物 | 3-(Methacryloyloxy)-2-hydroxypropyl methyl-5-carbomethoxybicyclo-[2.2.1]hept-2-ene-6-carboxylate | HCID 20464889 | — |
反応手順
This acid ester (50 g) was heated with glycidyl methacrylate (40 g) at 100° C. in the presence of 0.27 g of tetramethylammonium chloride and 0.13 g of 2,6-di-tert.butyl-p-cresol until the epoxide content had fallen to a negligible level; the desired ester so formed was a viscous liquid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04440850 |
| 出典データセット | uspto-grants-1984_04 |
| ORD ID | ord-5a7f171be5fc4b768eb0eb9d95b8dd57 |
| 出典メモ | uspto-grants-1984_04 |