N-(2-Acetylthio-3-methylbenzoyl)-N-cyclopentylglycine → N-(2-Mercapto-3-methylbenzoyl)-N-cyclopentylglycine

HRID 325491ノート

反応式

HRID 325491 の反応式
C([S:4][C:5]1[C:22]([CH3:23])=[CH:21][CH:20]=[CH:19][C:6]=1[C:7]([N:9]([CH:14]1[CH2:18][CH2:17][CH2:16][CH2:15]1)[CH2:10][C:11]([OH:13])=[O:12])=[O:8])(=O)C>N>[SH:4][C:5]1[C:22]([CH3:23])=[CH:21][CH:20]=[CH:19][C:6]=1[C:7]([N:9]([CH:14]1[CH2:18][CH2:17][CH2:16][CH2:15]1)[CH2:10][C:11]([OH:13])=[O:12])=[O:8]

参加物

3

反応物 1

HCID 13298946N-(2-Acetylthio-3-methylbenzoyl)-N-cyclopentylglycine

生成物 1

HCID 20465231N-(2-Mercapto-3-methylbenzoyl)-N-cyclopentylglycine

試薬・触媒・溶媒 1

HCID 222Ammonia溶媒

実験手順

To a chilled solution of methanolic ammonia (30 ml) was added 2.6 g (0.0078 mole) of N-(2-acetylthio-3-methylbenzoyl)-N-cyclopentylglycine. The reaction was covered with a nitrogen atmosphere and stirred three hours while warming slowly from 0° C. to room temperature.

後処理

  1. temperaturewhile warming slowly from 0° C. to room temperature

出典と根拠

ORDレコード
ord-e432d0224b8049d28d5e95380af8a551
出典データセット
uspto-grants-1984_04
特許番号
US04440941

反応ノート

読み込み中…