3-Bromobenzaldehyde → N-((3-bromophenyl)(tosyl)methyl)formamide

反応式

I[C:2]1[CH:3]=[C:4]([CH:8]([NH:19][CH:20]=[O:21])[S:9]([C:12]2[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][CH:13]=2)(=[O:11])=[O:10])[CH:5]=[CH:6][CH:7]=1.[Br:22]C1C=C(C=CC=1)C=O>>[Br:22][C:2]1[CH:3]=[C:4]([CH:8]([NH:19][CH:20]=[O:21])[S:9]([C:12]2[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][CH:13]=2)(=[O:11])=[O:10])[CH:5]=[CH:6][CH:7]=1

参加物

反応物 2

HCID 765833-Bromobenzaldehyde

HCID 85929703{(3-Iodophenyl)[(4-methylphenyl)sulfonyl]methyl}formamide

生成物 1

HCID 11337611N-((3-bromophenyl)(tosyl)methyl)formamide

実験手順

The title compound was prepared by a similar process to that described for Intermediate 52 but using 3-bromobenzaldehyde in place of 3-iodobenzaldehyde. Solid (11 g, 28%);

出典と根拠

ORDレコード: ord-f872f4fb719e4d759a1ec748eee6506a
出典データセット: uspto-grants-2008_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07427616B2

反応ノート

読み込み中…