Ammonia → 2-[(1,2-Dichloroethenyl)oxy]benzene-1-sulfonamide
反応式
[Cl:1][C:2]([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[S:12](Cl)(=[O:14])=[O:13])=[CH:3][Cl:4].O.[NH3:17]>C(Cl)Cl>[Cl:1][C:2]([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[S:12]([NH2:17])(=[O:14])=[O:13])=[CH:3][Cl:4]参加物
5
実験手順
A solution of 17.5 g of 2-(1,2-dichlorovinyloxy)phenylsulfonyl-chloride in 150 ml of methylenechloride is added slowly to a mixture of 30 ml of methylene chloride, 50 ml of water and 50 ml of 30% aqueous ammonia. The reaction mixture is stirred for 6 hours at a temperature of 20°-25° C. The organic phase is washed with water, dried over sodium sulfate and evaporated to a volume of 40 ml. The crystallised 2-(1,2-dichlorovinyloxy)phenylsulfonamide is separated and dried. Yield: 12.5 g, m.p. 147°-149° C.
後処理
- washThe organic phase is washed with water
- dry with materialdried over sodium sulfate
- customevaporated to a volume of 40 ml
- customThe crystallised 2-(1,2-dichlorovinyloxy)phenylsulfonamide is separated
- customdried
出典と根拠
- ORDレコード
- ord-9a4244b6d8bf42b5b6fc52a1cd35348c
- 出典データセット
- uspto-grants-1984_04
- 特許番号
- US04443245
反応ノート
読み込み中…