化工社化工社 化学情報印刷レポート · 研究参考用
6-Hydroxymethylquinoline → 6-Quinolinecarbaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 6-Hydroxymethylquinoline | HCID 1514385 | — |
| 触媒 | HCID 178418406 | HCID 178418406 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | 6-Quinolinecarbaldehyde | HCID 765653 | 82.7% |
反応手順
A mixture of 34 parts of 6-quinolinemethanol, 70 parts of manganese(IV)oxide and 300 parts of trichloromethane was stirred for 24 hours at room temperature. The reaction mixture was filtered over diatomaceous earth and the filtrate was evaporated, yielding 27.7 parts (82.7%) of 6-quinolinecarboxaldehyde; mp. 72° C. (interm. 16).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05268380 |
| 出典データセット | uspto-grants-1993_12 |
| ORD ID | ord-f0636ddc50f9408ab8832b5a92269345 |
| 出典メモ | uspto-grants-1993_12 |