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Phenyl Trifluoromethanesulfonate → 2-Triethylsilyl-5-phenyl-4-furaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Phenyl Trifluoromethanesulfonate | HCID 548641 | — |
| 反応物 | 3-Furancarboxaldehyde, 5-(triethylsilyl)- | HCID 10878438 | — |
| 反応物 | HCID 178506926 | HCID 178506926 | — |
| 触媒 | Zincchloride | HCID 3007855 | — |
| 触媒 | Tetrakis(triphenylphosphine)palladium | HCID 11979704 | — |
| 生成物 | 2-Triethylsilyl-5-phenyl-4-furaldehyde | HCID 19433144 | — |
反応手順
Treatment of 2-triethylsilyl-4-furaldehyde with lithio N,N,N'-trimethylethylenediamine, followed by phenyl trifluoromethanesulfonate in the presence of anhydrous zinc chloride and tetrakis (triphenylphosphine) palladium (O) provides the titled aldehyde.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05268387 |
| 出典データセット | uspto-grants-1993_12 |
| ORD ID | ord-4033900a3030452cba0b5a58789e3a38 |
| 出典メモ | uspto-grants-1993_12 |