関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Carbamic acid, ethyl ester | HCID 5641 | — |
| 反応物 | 2-Ethylhexyl glycidyl ether | HCID 17162 | — |
| 反応物 | Di-n-butyldilauryltin | HCID 9809426 | — |
| 触媒 | N,N-Dimethylbenzylamine | HCID 7681 | — |
| 生成物 | 5-(2-Ethylhexyl) oxymethyl-2-oxazolidinone | HCID 67684775 | 88% |
反応手順
8.9 g (0.10 mole) of ethyl carbamate was dissolved in 18.6 g (0.10 mole) of 2-ethylhexyl glycidyl ether. After adding 0.41 g of N, N-dimethylbenzylamine and 0 63 g of di-n-butyltin dilaurate, the solution was heated at 160° C. for 1 hour while blowing nitrogen gas into the reaction mixture. The product was distilled under reduced pressure to give 20.0 g (88% of theory) of 5-(2-ethylhexyl) oxymethyl-2-oxazolidinone.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05268484 |
|---|
| 出典データセット | uspto-grants-1993_12 |
|---|
| ORD ID | ord-c388f809cda045e386d237f8b7d3cc00 |
|---|
| 出典メモ | uspto-grants-1993_12 |
|---|
