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Dimethylformamide → Acrylic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethylformamide | HCID 6228 | — |
| 反応物 | 4-(1-Methylpropoxy)phenyl 4-(12-bromododecyloxy)benzoate | HCID 19734059 | — |
| 生成物 | Acrylic Acid | HCID 6581 | — |
| 生成物 | Tetramethylammonium hydroxide | HCID 60966 | — |
反応手順
A solution of 6 mmol (3.2 g) of the bromo compound obtained in (2), 10 mmol (0.72 g) of acrylic acid, and 10 mmol (1.8 g) of tetramethylammonium hydroxide (pentahydrate) in 30 ml of DMF was stirred for 10 hours at room temperature. To the resulting reaction solution was added water and then extracted with ether. The extract was concentrated, and the concentrate was purified by column chromatography to obtain 2.2 g of the objective monomer (3b). (Yield: 71%)
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05271866 |
| 出典データセット | uspto-grants-1993_12 |
| ORD ID | ord-b7348a1330274d1c8b19a7da8498f468 |
| 出典メモ | uspto-grants-1993_12 |