反応式
C(C([C:7]([C:10]([CH2:13][OH:14])([F:12])[F:11])([F:9])[F:8])(F)F)(F)F.N#N.C(C(CF)(F)F)(F)(F)[F:18]>>[C:7]([C:10]([CH2:13][OH:14])([F:12])[F:11])([F:18])([F:9])[F:8]参加物
4
反応条件
- 温度
- 277 °C
実験手順
The same catalyst was used from Example 4 above. The reactor was cooled to 277° C. The alcohol (CF3CF2CH2OH) flow of 0.49 mL/hr (2.0 sccm, 3.3×10-8 m3 /s), the COCl2 flow of 3.0 sccm (5.0×10-8 m3 /s), the HF flow of 7.0 sccm (1.2×10-7 m3 /s), and an N2 flow of 2 sccm (3.3×10-8 m3 /s) were begun. The gaseous effluent was analyzed by GCMS and found to be 89.3-90.5% CF3CF2CH2F over a 2 hour period with no evidence for catalyst deactivation.
後処理
- customover a 2 hour
出典と根拠
- ORDレコード
- ord-3ed5a220072b4a1580d3ff695cd26d85
- 出典データセット
- uspto-grants-1993_12
- 特許番号
- US05274189
関連ノート
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