Nitrogen → 2,2,3,3,3-Pentafluoropropanol

反応式

C(C([C:7]([C:10]([CH2:13][OH:14])([F:12])[F:11])([F:9])[F:8])(F)F)(F)F.N#N.C(C(CF)(F)F)(F)(F)[F:18]>>[C:7]([C:10]([CH2:13][OH:14])([F:12])[F:11])([F:18])([F:9])[F:8]

参加物

反応物 3

HCID 947Nitrogen

HCID 96412,2,3,3,4,4,5,5-Octafluoro-1-pentanol

HCID 5222821,1,1,2,2,3-Hexafluoropropane

生成物 1

HCID 98722,2,3,3,3-Pentafluoropropanol

反応条件

温度: 277 °C

実験手順

The same catalyst was used from Example 4 above. The reactor was cooled to 277° C. The alcohol (CF3CF2CH2OH) flow of 0.49 mL/hr (2.0 sccm, 3.3×10-8 m3 /s), the COCl2 flow of 3.0 sccm (5.0×10-8 m3 /s), the HF flow of 7.0 sccm (1.2×10-7 m3 /s), and an N2 flow of 2 sccm (3.3×10-8 m3 /s) were begun. The gaseous effluent was analyzed by GCMS and found to be 89.3-90.5% CF3CF2CH2F over a 2 hour period with no evidence for catalyst deactivation.