Phosgene → 1-Imidazolidinecarbonyl chloride, 2-thioxo-

HRID 328261ノート

反応式

HRID 328261 の反応式
C[Si](C)(C)[N:3]1[CH2:7][CH2:6][NH:5][C:4]1=[S:8].[C:11](Cl)([Cl:13])=[O:12]>C(Cl)Cl>[Cl:13][C:11]([N:3]1[CH2:7][CH2:6][NH:5][C:4]1=[S:8])=[O:12]

参加物

4

反応物 2

HCID 6371PhosgeneHCID 12472499HCID 12472499、化合物

生成物 1

HCID 129003221-Imidazolidinecarbonyl chloride, 2-thioxo-

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒3 回

反応条件

温度
0 °C

実験手順

50 parts by weight of 1-trimethylsilyl-imidazolidine-2-thione in 150 parts by volume of methylene chloride were treated with 35 parts by weight of phosgene in 50 parts by volume of methylene chloride over the course of 2 hours at 0° C. The mixture was stirred for 24 hours at 0° C, the methylene chloride was subsequently stripped off, and the residue was dried in a high vacuum. Semi-solid mass, incompletely soluble in aceteone. Crude yield: 97% IR bands at 1830, 1590 and 1240 cm-1.

後処理

  1. customthe residue was dried in a high vacuum

出典と根拠

ORDレコード
ord-49d1e9d5bfec442dae02ea421d6a6d15
出典データセット
uspto-grants-1977_04
特許番号
US04016282

反応ノート

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