Oxalic Acid → HCID 178526029、化合物

HRID 328658

反応式

HRID 328658 の反応式
[O-2].[O-2].[O-2].[O-2].[O-2].[V+5:6].[V+5].[C:8]([OH:13])(=[O:12])[C:9]([OH:11])=[O:10]>[O-2].[O-2].[O-2].[K+].[Nb+5].O>[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[V+5:6].[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[V+5:6]

参加物

5

反応物 2

HCID 971Oxalic AcidHCID 178419084HCID 178419084、化合物

生成物 1

HCID 178526029HCID 178526029、化合物

試薬・触媒・溶媒 2

HCID 160967Niobium potassium oxide触媒HCID 962Water溶媒

反応条件

温度
1300 °C

実験手順

Granulated alumina (8-16 mesh) is heated at 1300° C. for 4 hours. Potassium niobate (4K2O.3Nb2O5.16H2O) and vanadium pentoxide are suspended in 5 parts of water, heated to 80° C., and oxalic acid is added slowly to obtain a blue-colored vanadium oxalate solution. Sodium carbonate is added and the alumina is also placed in the solution. The mixture is dried over a water bath with agitation. While air is pumped in, it is indurated in a furnace at 400° C. for 16 hours to obtain the catalyst ready for use after cooling.

後処理

  1. temperatureheated to 80° C.

出典と根拠

ORDレコード
ord-caae455ae7444cb6abd1a6f8473d7d88
出典データセット
uspto-grants-1977_04
特許番号
US04018713

関連ノート

読み込み中…