Sodium Acetate → 5-(2-Carboxy-3-methoxybenzylidene)rhodanine
反応式
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][CH:6]=[C:7]([CH:12]=O)[C:8]=1[C:9]([OH:11])=[O:10].[S:14]1[CH2:20][C:18](=[O:19])[NH:17][C:15]1=[S:16].C([O-])(=O)C.[Na+]>C(O)(=O)C>[C:9]([C:8]1[C:3]([O:2][CH3:1])=[CH:4][CH:5]=[CH:6][C:7]=1[CH:12]=[C:20]1[S:14][C:15](=[S:16])[NH:17][C:18]1=[O:19])([OH:11])=[O:10]参加物
5
実験手順
To a stirred hot solution of 2.10 g. (11.65 mM) of 6-methoxyphthalaldehydic acid and 1.57 g. (11.75 mM) of rhodanine in 8 ml. of acetic acid is added 3.12 g. (38.1 mM) of sodium acetate. The resulting solution is refluxed 0.5 hour and then poured into ice water to give a tan precipitate. The solid is collected and partially air-dried to give 5-(2-carboxy-3-methoxybenzylidene)rhodanine as a tan solid.
後処理
- temperatureThe resulting solution is refluxed 0.5 hour
- customto give a tan precipitate
- customThe solid is collected
- custompartially air-dried
出典と根拠
- ORDレコード
- ord-8377a3225c814ae68d85ac165e05c747
- 出典データセット
- uspto-grants-1977_04
- 特許番号
- US04018891
反応ノート
読み込み中…