Azelaic Acid → Diprop-1-en-2-yl nonanedioate

HRID 329247

反応式

HRID 329247 の反応式
[C:1]([OH:13])(=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:9]([OH:11])=[O:10]>C(Cl)Cl>[C:1]([O:13][C:5]([CH3:6])=[CH2:4])(=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:9]([O:11][C:2]([CH3:3])=[CH2:1])=[O:10]

参加物

3

反応物 1

HCID 2266Azelaic Acid

生成物 1

HCID 23466330Diprop-1-en-2-yl nonanedioate

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

Azelaic acid (100 grams, 0.53 mole), methylene chloride (500 ml.) and mercuric acetate (18.2 grams, 0.057 mole) are treated with 1 ml. of boron trifluoride etherate, and propyne gas is bubbled through the mixture for 3 hours. Solid sodium bicarbonate (5 grams) is added, and the mixture is filtered free of solids and metallic mercury.

後処理

  1. customof boron trifluoride etherate, and propyne gas is bubbled through the mixture for 3 hours
  2. additionSolid sodium bicarbonate (5 grams) is added
  3. filtrationthe mixture is filtered free of solids and metallic mercury

出典と根拠

ORDレコード
ord-7e0bf1f8d03f4384b7b8d833b3bfe3a2
出典データセット
uspto-grants-1977_04
特許番号
US04020123

関連ノート

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