Toluene → 1-Hexene
反応式
Cl[C:2]1(Cl)[C:6](Cl)=[C:5](Cl)[C:4](Cl)=[C:3]1Cl.[C:12]1(C)[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>>[CH2:17]=[CH:12][CH2:13][CH2:14][CH2:15][CH3:16].[CH2:13]=[CH:12][CH2:17][CH2:2][CH2:6][CH2:5][CH:4]=[CH2:3]参加物
4
実験手順
A copolymer of 1-hexene and 1,7-octadiene (molar charge ratio 90:10) was synthesized according to the general procedure in Example I. It had an inherent viscosity of 3.5 dl./g. and 25 percent gel. A solution of 43.3 grams of this copolymer and 95 grams of hexachlorocyclopentadiene in 750 ml. toluene containing finely dispersed gel was heated at 110° C. for 24 hours. After cooling, the reaction mixture was precipitated in excess methanol. The yield of the product was 51.5 grams, inherent viscosity 1.5 dl./g., gel 16 percent. An acetone-extracted sample contained 14.1 percent chlorine, indicating that about 70 percent of the double bonds in the original copolymer had reacted with hexachlorocyclopentadiene.
後処理
- temperature