1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine → [[2-[(Dimethylamino)methyl]phenyl]diphenylphosphoranylidene]carbamic acid, methyl ester
反応式
[C:1]1([P:7]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=2[CH2:14][N:15]([CH3:17])[CH3:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:24]([N:28]=[N+]=[N-])(=[O:27])[O:25][CH3:26]>CCOCC>[CH3:16][N:15]([CH2:14][C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=1[P:7](=[N:28][C:24](=[O:27])[O:25][CH3:26])([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)[CH3:17]参加物
4
実験手順
A 2.0 g portion of 2-(diphenylphosphino)-N,N-dimethylbenzenemethanamine was reacted with 4.0 ml of 1M methyl carbonazidate in ether as described in Example 1, giving 1.32 g of the desired product, mp 95°-97° C.