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Pyridine → 1-(2-Hexyl-4-tetradecylphenoxy)-3-(triphenylmethoxy)-2-propanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pyridine | HCID 1049 | — |
| 反応物 | Trityl chloride | HCID 6456 | — |
| 反応物 | 3-(2-Hexyl-4-tetradecylphenoxy)-1,2-propanediol | HCID 14819670 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | 1-(2-Hexyl-4-tetradecylphenoxy)-3-(triphenylmethoxy)-2-propanol | HCID 15030267 | 81.4% |
反応手順
A mixture of 11.64 g of 3-(2-hexyl-4-tetradecylphenoxy)-1,2-propanediol, 12.32 g of trityl chloride and 40 ml of pyridine was stirred for 24 hours, then diluted with chloroform, washed with aqueous sodium bicarbonate, water, dried and the solvents evaporated under reduced pressure. The residue was coevaporated with toluene, giving 14.6 g of the desired compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04894367 |
| 出典データセット | uspto-grants-1990_01 |
| ORD ID | ord-da58882123674abc8b7bdf19bf7112ce |
| 出典メモ | uspto-grants-1990_01 |