Putrescine → 1-(4-Aminobutylamino)-4-methoxyanthracene-9,10-dione

関与物質

役割	名称	HCID	仕込み量
反応物	Putrescine	HCID 1045	—
反応物	1,4-Dimethoxyanthraquinone	HCID 266054	—
溶媒	Dichloromethane	HCID 6344	—
生成物	1-(4-Aminobutylamino)-4-methoxyanthracene-9,10-dione	HCID 13380578	50.8%

反応手順

1,4-Diaminobutane (1.65 g, 19 mmol) was added to a solution of 1,4-dimethoxyanthracene-9,10-dione (1.0 g, 3.7 mmol) in CH2Cl2 (700 ml). After seven, hours of irradiation, the solvent was removed and the residue chromatographed on silica gel. Starting material was eluted with CHCl3 and the product with 5% CH3OH in CHCl3. A purple solid (0.61 g, 50%) was obtained which was converted to the benzyloxycarbonyl derivative.

情報源と証拠

DOI	10.6084/m9.figshare.5104873.v1
特許番号	US04894451
出典データセット	uspto-grants-1990_01
ORD ID	ord-cb9650b945854228a55b0887a0509362
出典メモ	uspto-grants-1990_01