化工社化工社 化学情報印刷レポート · 研究参考用
2-Hydroxy-4-nitrobenzyl alcohol → 2-Hydroxy-4-nitrobenzaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Hydroxy-4-nitrobenzyl alcohol | HCID 11816094 | — |
| 触媒 | HCID 178418406 | HCID 178418406 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | 2-Hydroxy-4-nitrobenzaldehyde | HCID 75570 | — |
反応手順
6.0 g (35.5 mmol) of 2-(hydroxymethyl)-5-nitrophenol and 3.1 g (35.5 mmol) of activated manganese (IV) oxide in 100 ml of chloroform are heated under reflux for 20 h. The mixture is filtered through kieselguhr, concentrated and dried under high vacuum. The title compound is directly reacted further.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08884017B2 |
| 出典データセット | uspto-grants-2014_11 |
| ORD ID | ord-5e2f55c3259946c9a79615d1315f222b |
| 出典メモ | uspto-grants-2014_11 |