1,10-Phenanthroline → Copper Bis(1,10-phenanthroline) Sulfate

HRID 342364

反応式

HRID 342364 の反応式
[S:1]([O-:5])([O-:4])(=[O:3])=[O:2].[Cu+2:6].O.[N:8]1[C:21]2[C:12](=[CH:13][CH:14]=[C:15]3[C:20]=2[N:19]=[CH:18][CH:17]=[CH:16]3)[CH:11]=[CH:10][CH:9]=1.[N:22]1[C:35]2[C:26](=[CH:27][CH:28]=[C:29]3[C:34]=2[N:33]=[CH:32][CH:31]=[CH:30]3)[CH:25]=[CH:24][CH:23]=1>O>[S:1]([O-:5])([O-:4])(=[O:3])=[O:2].[N:8]1[C:21]2[C:12](=[CH:13][CH:14]=[C:15]3[C:20]=2[N:19]=[CH:18][CH:17]=[CH:16]3)[CH:11]=[CH:10][CH:9]=1.[N:22]1[C:35]2[C:26](=[CH:27][CH:28]=[C:29]3[C:34]=2[N:33]=[CH:32][CH:31]=[CH:30]3)[CH:25]=[CH:24][CH:23]=1.[Cu+2:6]

参加物

5

反応物 3

HCID 13181,10-Phenanthroline2 回HCID 212261,10-Phenanthroline hydrateHCID 24462Copper Sulfate

生成物 1

HCID 69646830Copper Bis(1,10-phenanthroline) Sulfate

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

The following describes the preparation of a 10 mM stock solution of Cu(phenanthroline)2SO4. To a 100 mL of distilled water, in an Erlenmeyer flask, was added 162 mg (1.0 mmol) of anhydrous copper sulfate (Aldrich Chemical Company, Inc., Milwaukee, Wis.). The solid immediately caked into pale blue chunks on the bottom of the Erlenmeyer flask. Upon swirling of the Erlenmeyer flask, these pale blue chunks slowly dissolved. To this solution was added 399 mg (2.0 mmol) of 1,10-phenanthroline hydrate (Aldrich Chemical Company, Inc. supra.). At this point, there were needles of phenanthroline floating atop the aqueous suspension. These needles of phenanthroline were dissolved by sonication for 5 minute in a Branson M2200 sonicator. The resulting solution was an aquamarine blue, 10 mM solution of Cu(phenanthroline)2SO4. Using a Beckman DU70 spectrophotometer, the A720 of this solution was found to be 0.61 O.D.

後処理

  1. dissolutionthese pale blue chunks slowly dissolved

出典と根拠

ORDレコード
ord-df58b9f7bf25490fae13f15615976821
出典データセット
uspto-grants-1999_01
特許番号
US05858650

関連ノート

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