Benzyl Bromide → 1-benzyl-5-hydroxyiminomethyl-2,4(1H,3H)-pyrimidinedione

反応式

[OH:1][N:2]=[CH:3][C:4]1[C:5](=[O:11])[NH:6][C:7](=[O:10])[NH:8][CH:9]=1.[CH2:12](Br)[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[CH2:12]([N:8]1[CH:9]=[C:4]([CH:3]=[N:2][OH:1])[C:5](=[O:11])[NH:6][C:7]1=[O:10])[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1

参加物

反応物 2

HCID 7498Benzyl Bromide

HCID 2687545-hydroxyiminomethyl-2,4(1H,3H)-pyrimidinedione

生成物 1

HCID 867535631-benzyl-5-hydroxyiminomethyl-2,4(1H,3H)-pyrimidinedione

実験手順

substituting 5-hydroxyiminomethyl-2,4(1H,3H)-pyrimidinedione and benzyl bromide gave 1-benzyl-5-hydroxyiminomethyl-2,4(1H,3H)-pyrimidinedione, m.p. 172°-174° C.; and

出典と根拠

ORDレコード: ord-b66c335f0fbf4d78947438529fadb45c
出典データセット: uspto-grants-1999_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05859014

反応ノート

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