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Formamide → 4-(N-formylaminomethyl)benzophenone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Formamide | HCID 713 | — |
| 反応物 | Sodium Carbonate | HCID 10340 | — |
| 反応物 | 4-(Chloromethyl)benzophenone | HCID 3016376 | — |
| 反応物 | Sodium Diformylamide | HCID 10877056 | — |
| 溶媒 | Sodium Methoxide | HCID 10942334 | — |
| 生成物 | 4-(N-formylaminomethyl)benzophenone | HCID 53721082 | — |
反応手順
150 g of formamide are stirred together with 90 mL of 30%ig sodium methylate solution for 8 hours under slight vacuum at 80° C. To the resulting solution of sodium diformylamide there are added 150 g of 4-chloromethylbenzophenone. After 15 hours the suspension originally present has changed to a clear solution which is added to 1l of 10%ig sodium carbonate solution. A solid material precipitates, which is filtered off in vacuo and dried.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05859084 |
| 出典データセット | uspto-grants-1999_01 |
| ORD ID | ord-f04bdcdffb864269893718aa61552b51 |
| 出典メモ | uspto-grants-1999_01 |