Methane → 1,1,1-Triphenyl-4-acetoxy-1-sila-2-butene

HRID 342857

反応式

HRID 342857 の反応式
[C:1]([O:4][CH:5]=[CH:6][CH:7]=C)(=[O:3])[CH3:2].[C:9]1([SiH:15]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C>C1(C)C=CC=CC=1>[C:22]1([Si:15]([C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:7]=[CH:6][CH2:5][O:4][C:1](=[O:3])[CH3:2])[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1

参加物

5

反応物 3

HCID 297MethaneHCID 151951,3-Butadienyl acetateHCID 69922Triphenylsilane

生成物 1

HCID 538005221,1,1-Triphenyl-4-acetoxy-1-sila-2-butene

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

A solution of 1-acetoxy-1,3-butadiene (0.1 mol), triphenylsilane (0.1 mol), and Rh2Cl2 (CO)4 (194.5 mg, 0.625 mol) in 100 mL of toluene was stirred at room temperature under argon for 3 days. The reaction mixture is treated with decolorizing charcoal, and the mixture boiled briefly. After cooling, the reaction mixture is filtered through Celite. Concentration of the solution will afford the title compound.

後処理

  1. temperatureAfter cooling
  2. filtrationthe reaction mixture is filtered through Celite

出典と根拠

ORDレコード
ord-a1c7979ee9ed4078a2a53bd54710432e
出典データセット
uspto-grants-1999_01
特許番号
US05859232

関連ノート

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