Hydrogen Peroxide → 3'-Fluoro-4'-(octyloxy)[1,1'-biphenyl]-4-ol

反応式

[F:1][C:2]1[CH:3]=[C:4]([C:17]2[CH:22]=[CH:21][C:20](B(O)O)=[CH:19][CH:18]=2)[CH:5]=[CH:6][C:7]=1[O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[OH:26]O>>[F:1][C:2]1[CH:3]=[C:4]([C:17]2[CH:22]=[CH:21][C:20]([OH:26])=[CH:19][CH:18]=2)[CH:5]=[CH:6][C:7]=1[O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

参加物

反応物 2

HCID 784Hydrogen Peroxide

HCID 10569430HCID 10569430、化合物

生成物 1

HCID 37550353'-Fluoro-4'-(octyloxy)[1,1'-biphenyl]-4-ol

実験手順

This was prepared using a similar method to that described for compound 12. Quantities: 3-fluoro-4-octoxybiphenyl-4'-yl-boronic acid (11) (4.40 g, 0.012 mol), 10% hydrogen peroxide (16 ml, 0.036 mol).

後処理

customThis was prepared

出典と根拠

ORDレコード: ord-8c36378b18b4432982e5272644c91008
出典データセット: uspto-grants-1999_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05861109

反応ノート

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