化工社化工社 化学情報印刷レポート · 研究参考用
Diethyl Ether → 9-Octadecenal, (9Z)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Diethyl Ether | HCID 3283 | — |
| 反応物 | Oleyl Alcohol | HCID 5284499 | — |
| 反応物 | HCID 178418287 | HCID 178418287 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 9-Octadecenal, (9Z)- | HCID 5364492 | 90.1% |
反応手順
An 18 g portion of pyridinium chlorochromate was slurried in 200 ml of dichloromethane. A solution of 15 g of oleyl alcohol in 200 ml of dichloromethane was added. This mixture was stirred for 4 hours, then poured into ether and filtered through hydrous magnesium silicate. The filtrate was evaporated, giving 13.42 g of the desired compound as a colorless liquid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05053426 |
| 出典データセット | uspto-grants-1991_10 |
| ORD ID | ord-0a27b92f0b3f46f8b3c80fea1702af49 |
| 出典メモ | uspto-grants-1991_10 |