Dichloromaleic anhydride → N,N-bis-(3-chloroallyl) dichloromaleic monoamide

HRID 34509ノート

反応式

HRID 34509 の反応式
[Cl:1][C:2]1=[C:3]([Cl:9])[C:4]([O:6][C:7]1=[O:8])=[O:5].[Cl:10][CH:11]=[CH:12][CH2:13][NH:14][CH2:15][CH:16]=[CH:17][Cl:18]>C(Cl)Cl>[Cl:10][CH:11]=[CH:12][CH2:13][N:14]([CH2:15][CH:16]=[CH:17][Cl:18])[C:4](=[O:5])/[C:3](/[Cl:9])=[C:2](/[Cl:1])\[C:7]([OH:6])=[O:8]

参加物

4

反応物 2

HCID 70728Dichloromaleic anhydrideHCID 53981628Bis-(3-chloroallyl)amine

生成物 1

HCID 86742314N,N-bis-(3-chloroallyl) dichloromaleic monoamide収率 99.1%

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

Dichloromaleic anhydride (1.7 g, 0.01 mol) and 30 ml methylene chloride were stirred under a mild reflux. Bis-(3-chloroallyl)amine (1.7 g, 0.01 mol) was then added. The exothermic reaction yielded a clear solution. The solution was stirred at room temperature for 3 hours. The mixture was stripped, resulting in 3.3 g of the above-named product.

後処理

  1. customThe exothermic reaction
  2. customyielded a clear solution

出典と根拠

ORDレコード
ord-5050602a882a45ac90f3b09ce19acbb6
出典データセット
uspto-grants-1988_08
特許番号
US04762548

反応ノート

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